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化工英文文献翻译
In contrast to the complexation of H2tsalamo with nickel-
(II) acetate, the reaction of the oxygen analogue, H2salamo,
with nickel(II) acetate gave a trinuclear complex [Ni3-
(salamo)2(OAc)2(EtOH)2] (Figure 3).23,24 All the nickel atoms
of the complex have an octahedral geometry. A similar
trinuclear complex was obtained from zinc(II) acetate and
H2salamo, although no ethanol molecules coordinate to the
metals bound in the ligand.11b
Interestingly, binding behavior of the methoxy analogue
H2(3-MeOsalamo) toward nickel(II) is strikingly different
from that of H2salamo to give a mononuclear complex [Ni-
(3-MeOsalamo)(H2O)2] upon the complexation (Figure 4).25
The nickel atom has an octahedral geometry possessing water molecules at the two axial sites. Noteworthy is that complexation
of H2(3-MeOsalamo) with zinc(II) acetate afforded
the corresponding trinuclear complex.11b
In conclusion, we have synthesized and isolated a new
oxime-type N2S2 ligand, H2tsalamo, which is much more
stable than the imine analogue, H2tsalen. The tsalamo gave
the mononuclear nickel(II) complex [Ni(tsalamo)] as seen
in the imine analogues. The tsalamo unit would be a useful
building block for metallo-supramolecules to incorporate an
N2S2 chelate site. Further investigation on the tsalamocomplexes
of other transition metals such as manganese,
cobalt, iron, etc. is now in progress.
直接在线翻译的就算了啊 我也会 可是 好多不通啊
In contrast to the complexation of H2tsalamo with nickel-
(II) acetate, the reaction of the oxygen analogue, H2salamo,
with nickel(II) acetate gave a trinuclear complex [Ni3-
(salamo)2(OAc)2(EtOH)2] (Figure 3).23,24 All the nickel atoms
of the complex have an octahedral geometry. A similar
trinuclear complex was obtained from zinc(II) acetate and
H2salamo, although no ethanol molecules coordinate to the
metals bound in the ligand.11b
Interestingly, binding behavior of the methoxy analogue
H2(3-MeOsalamo) toward nickel(II) is strikingly different
from that of H2salamo to give a mononuclear complex [Ni-
(3-MeOsalamo)(H2O)2] upon the complexation (Figure 4).25
The nickel atom has an octahedral geometry possessing water molecules at the two axial sites. Noteworthy is that complexation
of H2(3-MeOsalamo) with zinc(II) acetate afforded
the corresponding trinuclear complex.11b
In conclusion, we have synthesized and isolated a new
oxime-type N2S2 ligand, H2tsalamo, which is much more
stable than the imine analogue, H2tsalen. The tsalamo gave
the mononuclear nickel(II) complex [Ni(tsalamo)] as seen
in the imine analogues. The tsalamo unit would be a useful
building block for metallo-supramolecules to incorporate an
N2S2 chelate site. Further investigation on the tsalamocomplexes
of other transition metals such as manganese,
cobalt, iron, etc. is now in progress.
直接在线翻译的就算了啊 我也会 可是 好多不通啊
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