酸碱盐混一起时,谁先与谁反应?还有,溶液与溶液之间怎么判断鉴别顺序

问题描述:

酸碱盐混一起时,谁先与谁反应?还有,溶液与溶液之间怎么判断鉴别顺序
1)比如说,有Mg(SO)4与H2SO4的混合品,这时不断将NaOH加入其中,那么NaOH会先与Mg(SO)4反应,还是先与H2SO4反应?
2)还有,请问K2CO3、H2SO4、HNO3、BaCl2这四种溶液(仅用同组溶液间相互反应鉴别)的鉴别顺序是怎样的?
2个回答 分类:综合 2014-10-05

问题解答:

我来补答
发现中学生对这两个问题都有很大的迷惑.不管怎么说能问这样的问题就说明你真正的思考过这些问题.
对于第一个.应该这么说,氢氧化钠会和两个化合物同时反应.但是我们看到的结果是先和硫酸反应.为什么呢,因为即使氢氧化钠先和硫酸镁反应,生成氢氧化镁,只要硫酸没有反应完,马上两者就会反应,沉淀消失.只要硫酸没有反应完,那么生成的氢氧化镁都会再消失.所以,你要知道,若说谁先反应,肯定是同时反应,但是对于结果来看,是先和硫酸反应.
第二题:也是没办法说谁先检出.就好像四瓶溶液你不知道是什么,也就不知道先看到气体啊还是先看到沉淀.你如果幸运,把一个溶液分别加入另外三个,有两个有气体放出,则你拿到的是碳酸钾;如果有两个沉淀出现呢,则你拿到的是氯化钡.因为你不知道你首先拿的是什么,所以也不能够确定那个先检出,你说对吗?当然我举的是极端例子,但是也不能说我说的不存在吧.
 
 
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